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Material Safety Data Sheet

Revised: 7/16/1995

Similar to Form OSHA-20

ORTHOTOLIDINE

Fuller Engineering Inc. · · · Telephone Number: (714) 502-0700

Address: 975 E. Orangefair Lane · Anaheim, CA 92801

3E Company · 24-hour Emergency Phone · (800) 451-8346

Section I: Product Identification:

Chemical Name and Synonyms:

Orthotolidine

Trade Name and Synonyms:

Orthotolidine

Chemical Family:

Acidic aromatic halogen solution.

Formula:

Not applicable.

Section II: Ingredients

Chemical Name

CAS Number

Hydrochloric Acid

7647-01-0

*Orthotolidine Dihydrochloride

612-82-8

*This chemical is subject to the reporting requirements of SARA Title III Section 313 and 40 CFR 372.

Section III: Physical Data

Boiling Point (°F):

212 degrees Fahrenheit

Vapor Pressure (mm Hg):

17

Vapor Density (Air = 1):

0.6

Percent Volatile by Volume:

99

Solubility in Water:

Infinite

Evaporative Rate (H2O = 1):

No data

Specific Gravity (H2O = 1):

1.03

Appearance and Odor:

Clear, slight yellow, odorless solution.

Section IV: Fire and Explosion Hazard Data

Flash Point (Closed Cup):

Flammable Limits:

Non-flammable

Lel: N/A Uel: N/A

Extinguishing Media:

Any media suitable for extinguishing the surrounding fire.

Special Fire Fighting Procedures:

Wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

Unusual Fire and Explosion Hazards:

Contact with metals may produce hydrogen gas, which is explosive. May emit toxic fumes of chlorine, hydrogen chloride.

Section V: Health Hazard Data

Airborne Exposure Limits: None established.

Toxicity:

ORTHOTOLIDINE DIHYDROCHLORIDE: LD50: 404 mg/kg.; TLV: 2 ppm (skin)

HYDROCHLORIC ACID: LD50: 900 mg/kg.; LC50: 3124 PPM/1h; TLV: 7mg/m3 (ceiling)

NFPA Codes: Health: 3 Flammability: 0 Reactivity: 0

Target Organs: Eyes, skin, respiratory tract.

Carcinogenic Effects: Listed as a carcinogen by IARC, NTP. Not listed as a carcinogen or suspected carcinogen by OSHA.

Mutagenic Effects: No data

Teratogenic Effects: No data

Developmental Toxicity: No data

Effects of Overexposure:

INHALATION: Inhalation of dusts or mists can irritate the respiratory tract.

INGESTION: Corrosive. May cause severe gastrointestinal irritation, cyanosis, headache, dizziness, burns of mouth, esophagus and stomach.

SKIN CONTACT: Corrosive. Contact may cause severe burns.

EYE CONTACT: Causes severe burns to eyes. Can result in permanent damage and/or vision loss.

Chronic Effect: No information found.

Emergency and First Aid Procedures:

INHALATION: Remove person to fresh air. Obtain medical assistance.

INGESTION: Never give anything by mouth to an unconscious person. Give large amounts of water with milk of magnesia. Call a physician. Do not induce vomiting.

SKIN CONTACT: Flood area with water for at least 15 minutes. Wash skin thoroughly with bakin soda, soap and water. Remove contaminated clothing and shoes. Wash clothing and clean shoes thoroughly before reuse. If symptoms persist, obtain medical assistance.

EYE CONTACT: Immediately flush eyes with plenty of water for at least 20 minutes while holding lids gently, but firmly, apart. Lift upper and lower lids occasionally to ensure thorough flushing under them. If symptoms persist, obtain medical assistance.

Medical Conditions Aggravated by Exposure: Eye, skin, and respiratory conditions.

Section VI: Reactivity Data

Stability:

Stable.

Conditions to Avoid:

Contact with metals generates explosive hydrogen.

Hazardous Decomposition Products:

None known.

Hazardous Polymerization:

Will not occur.

Section VII: Spill or Leak Procedures

Release or Spill Procedures:

Neutralize with soda ash. Absorb with vermiculite or other inert material. Containerize for later disposal.

Waste Disposal Method:

To be performed in compliance with all current local, state and federal regulations. Spills onto sand, soil, or other absorbent may be handled by placing the affected soil into approved containers then label and store for proper treatment or disposal.

Section VIII: Special Protection Information

Respiratory Protection:

NIOSH-MSHA approved air-supplied respirator as needed to remain under the TLVs.

Ventilation:

Well-ventilated area or chemical fume hood.

Protective gloves:

Rubber

Eye protection:

Safety goggles

Other Protective Equipment:

Laboratory clothing, eye bath and safety shower.

Section IX: Special Precautions

Handling and Storage:

Store bottles tightly capped and upright. Keep in a cool place away from direct sunlight and heat.

Other Precautions:

Avoid contact with eyes and skin.

DOT:

Not regulated.

The statements contained herein are offered as informational data only and are believed to be correct. However, this product should be handled by persons having related technical skills, and at their own discretion and risk. Since seller has no control over the use of this product, no warranty, expressed or implied, is made and seller assumes no liability in connection with any use of this information or from contact and/or handling of this product.

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Last modified: September 15, 2008